Synthesis methods of phosphorylated carbamide containing acyclic and heterocyclic compounds

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dc.contributor.author Bakibayev, A.A.
dc.contributor.author Zhumanov, K.B.
dc.contributor.author Panshina, S.Yu.
dc.contributor.author Gorbin, S.I.
dc.contributor.author Malkov, V.S.
dc.contributor.author Tsoy, I.G.
dc.contributor.author Massalimova, B.K.
dc.contributor.author Matniyazova, G.K.
dc.contributor.author Baybazarova, Е.А.
dc.date.accessioned 2019-11-04T03:59:33Z
dc.date.available 2019-11-04T03:59:33Z
dc.date.issued 2019-09-30
dc.identifier.citation Bakibayev, A.A. Synthesis methods of phosphorylated carbamide containing acyclic and heterocyclic compounds / A.A. Bakibayev, K.B. Zhumanov, S.Yu. Panshina [et al.] // Қарағанды универисетінің хабаршысы. Химия сериясы. = Вестник Карагандинского университета. Серия Химия. = Bulletin of the Karaganda University. Chemistry series. – 2019. - № 3. – P. 107-114. ru_RU
dc.identifier.issn 2518-718X
dc.identifier.issn 2663-4872
dc.identifier.uri http://rep.ksu.kz//handle/data/8628
dc.description.abstract In the paper, for the first time, an attempt of systematization of knowledge in the field of reactions of ureas and their heterocyclic derivatives with phosphorus containing reagents has been carried out. In the review due to the significant differences in the substrates and reagents used, methods for producing phosphorylated nitrogencontaining compounds according to their final structure are grouped in three directions of their formation — the synthesis of acyclic, monocyclic and bicyclic ureas. Thus, the methods for the production of acyclic N-phosphorylated ureas by reactions of the corresponding N-phosphoisocyanates with aliphatic and aromatic amines of various structures are considered, and rarely used alternative methods for the synthesis of such compounds are considered. An analysis of the known methods for the synthesis of phosphorylated monocyclic carbamidecontaining compounds suggests that: five-membered phosphazacycles, most of them are represented by imidazolidine structures, while tetracyclic phosphazacycles are diazaphosphetidinones, and six-membered phosphazacycles are diazophosphorins and triazaphophorphoryphorphoridine. The synthesized and studied phosphorylated bicyclic bisurea are represented by diphosphadione, diphosphaspirooctanedione, and phosphorylated tetraazabicyclo octionic structures. It was concluded that, on the basis of the systematization of the results of experimental studies on the methods of synthesis of phosphorylated ureas, it can be expected that their development will allow finding ways to obtain new highly effective drugs and synthons of their production. ru_RU
dc.language.iso en ru_RU
dc.publisher Ye.A.Buketov Karaganda State University Publishing house ru_RU
dc.relation.ispartofseries Қарағанды универисетінің хабаршысы. Химия сериясы. = Вестник Карагандинского университета. Серия Химия. = Bulletin of the Karaganda University. Chemistry series.;№ 3(95)/2019
dc.subject urea ru_RU
dc.subject phosphorylation ru_RU
dc.subject heterocyclic compounds ru_RU
dc.subject N-phosphoisocyanates ru_RU
dc.subject imidazolidines ru_RU
dc.subject diazaphosphetidinones ru_RU
dc.subject diazophosphorins ru_RU
dc.subject triazaphosphorinandionones ru_RU
dc.subject diphosphadiones ru_RU
dc.subject diphosphaspiroctanediones ru_RU
dc.subject phosphorylated tetraazibicyclooctandiones ru_RU
dc.subject glycoluryl ru_RU
dc.title Synthesis methods of phosphorylated carbamide containing acyclic and heterocyclic compounds ru_RU
dc.title.alternative Фосфорланған карбамидқұрамды ациклді және гетероциклді қосылыстарды синтездеу әдістері ru_RU
dc.title.alternative Методы синтеза фосфорилированных карбамидсодержащих ациклических и гетероциклических соединений ru_RU
dc.type Article ru_RU


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