EPR-spectroscopy of the fast proton exchange reactions in solutions

Masalimov, A.S.; Kurmanova, A.F.; Nikolskiy, S.N.; Ospanov, A.U.; Tur, A.A.

dc.contributor.author	Masalimov, A.S.
dc.contributor.author	Kurmanova, A.F.
dc.contributor.author	Nikolskiy, S.N.
dc.contributor.author	Ospanov, A.U.
dc.contributor.author	Tur, A.A.
dc.date.accessioned	2019-03-19T08:39:21Z
dc.date.available	2019-03-19T08:39:21Z
dc.date.issued	2014-03-29
dc.identifier.citation	EPR-spectroscopy of the fast proton exchange reactions in solutions / A.S.Masalimov [et al.] // Қарағанды универисетінің хабаршысы. ХИМИЯ Сериясы.=Вестник Карагандинского университета. Серия ХИМИЯ.=Bulletin of the Karaganda University. CHEMISTRY Series. – 2014. - № 1. - P.30-35.	ru_RU
dc.identifier.issn	0142-0843
dc.identifier.uri	http://rep.ksu.kz:80//handle/data/4476
dc.description.abstract	Kinetic parameters of the fast intermolecular proton exchange reactions between radical 3,6-di-tert.butyl-2- oxyphenoxyl and different H-acids in toluene solutions obtained by ESR spectroscopy method are presented. NH-acids have more protolytic reactivity than carboxylic acids. Values of various physico-chemical properties for some H-acids, such as ionization potential, electron affinity, proton affinity and energy of deprotonation were obtained by quantum chemical calculations in the program «Gaussian-2009».	ru_RU
dc.language.iso	en	ru_RU
dc.publisher	KSU Publ.	ru_RU
dc.relation.ispartofseries	Қарағанды универисетінің хабаршысы. ХИМИЯ Сериясы.=Вестник Карагандинского университета. Серия ХИМИЯ.=Bulletin of the Karaganda University. CHEMISTRY Series.;№ 1(73)/ 2014
dc.subject	EPR-spectroscopy	ru_RU
dc.subject	semiquinone radicals	ru_RU
dc.subject	H-acids	ru_RU
dc.subject	proton exchange reactions	ru_RU
dc.subject	quantum-chemical investigations	ru_RU
dc.title	EPR-spectroscopy of the fast proton exchange reactions in solutions	ru_RU
dc.title.alternative	Ерітінділердегі жылдам протон алмасу реакцияларының ЭПР-спектроскопиясы	ru_RU
dc.title.alternative	ЭПР-спектроскопия быстрых реакций протонного обмена в растворах	ru_RU
dc.type	Article	ru_RU