Abstract:
Kinetic parameters of the fast intermolecular proton exchange reactions between radical 3,6-di-tert.butyl-2-
oxyphenoxyl and different H-acids in toluene solutions obtained by ESR spectroscopy method are presented.
NH-acids have more protolytic reactivity than carboxylic acids. Values of various physico-chemical properties
for some H-acids, such as ionization potential, electron affinity, proton affinity and energy of
deprotonation were obtained by quantum chemical calculations in the program «Gaussian-2009».
