Abstract:
Kinetic and thermodynamic experimental parameters for the reactions of protonation of alkaloids by spin
probe 3,6-di-tert-butyl-2-oxyphenoxyl obtained by ESR spectroscopy in a toluene solution are presented.
Values of various physico-chemical data obtained by quantum chemical calculations in the «Gaussian-2009»
for some alkaloids, such as ionization potential, electron affinity and proton affinity have been calculated.