Protolytic Reactions of 3,6-DI-tert-Butyl-2-Hydroxyphenoxyl with Nitrogen Bases

Show simple item record Masalimov, A. S. Tur, A. A. Nikolskiy, S. N. 2018-01-30T07:21:03Z 2018-01-30T07:21:03Z 2016-03
dc.identifier.citation Masalimov A. S.Protolytic Reactions of 3,6-DI-tert-Butyl-2-Hydroxyphenoxyl with Nitrogen Bases/A. S. Masalimov, A. A. Tur, S. N. Nikolskiy//Theoretical and Experimental Chemistry.-2016.-№1(52).-pp 57–65 ru_RU
dc.identifier.issn 0040-5760
dc.description.abstract Stable phenoxyl radicals were used as spin probes for the EPR spectral determination of the kinetic basicity of amines, nitrogen heterocycles, alkaloids, and of rate constants for rapid intermolecular proton exchange with various NH-acids in nonaqueous media. An analysis was carried out on the effect of the solvation properties of the medium on the EPR spectral parameters of the components of acid–base reactions required for spectral kinetic investigations. ru_RU
dc.language.iso en ru_RU
dc.publisher Springer US ru_RU
dc.relation.ispartofseries Theoretical and Experimental Chemistry;№1(52)
dc.subject phenoxyl radical ru_RU
dc.subject protolytic reactions ru_RU
dc.subject EPR spectra ru_RU
dc.subject hyperfine coupling constants ru_RU
dc.subject proton transfer rate constant ru_RU
dc.subject nitrogen bases ru_RU
dc.subject ion pairs ru_RU
dc.title Protolytic Reactions of 3,6-DI-tert-Butyl-2-Hydroxyphenoxyl with Nitrogen Bases ru_RU
dc.type Article ru_RU

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